Mechanism of the Adsorption of Ammonium Ions from Aqueous Solution by a Chinese Natural Zeolite
نویسندگان
چکیده
The adsorption of ammonium ions onto a Chinese natural zeolite in an agitated batch adsorber was studied. A trial-and-error non-linear method was developed to examine two widely used isotherms, the Langmuir and Freundlich. The data gained from the adsorption system fitted the Freundlich isotherm better. An ion exchange model, describing the relationship among the total metal ions in the solution, NH4 þ removed from the solution, and ions initially released from the zeolite, was developed for the adsorption system. In addition, a parameter of the ion exchange potential was defined to describe the adsorption mechanism. Ion exchange was the main mechanism that accounted for the adsorption of ammonium ions onto the Chinese natural zeolite.
منابع مشابه
Ammonium Adsorption on Natural Zeolite (clinoptilolite): Adsorption Isotherms and Kinetics Modeling
A batch sorption process for removal of ammonium ions from aqueous solution using natural zeolite was studied. Tree different particle sizes of zeolite (1-2 mm, 2-4 mm and 4-10 mm) were used in the experiments. Sorption of ammonium ions on natural zeolite were carried out at 298 K with the initial concentrations of ammonium in the range of 1000 – 7000 mg NH4 -N/dm. Equilibrium data were fitted ...
متن کاملEvaluation of natural zeolite clinoptilolite efficiency for the removal of ammonium and nitrate from aquatic solutions
Background: Surface water and groundwater pollution with various forms of nitrogen such as ammonium and nitrate ions is one of the main environmental risks. The major objectives of this study were to evaluate the capacity of natural zeolite (clinoptilolite) to remove NO3- and NH4+ from polluted water under both batch and column conditions. Methods: The laboratory batch and column experiments we...
متن کاملStudies on optimization of efficient parameters for removal of lead from aqueous solutions by natural zeolite as a low-cost adsorbent using response surface methodology
In this research, the removal of lead from the aqueous solution was investigated using natural nontoxic zeolite (clinoptilolite) as a low-cost adsorbent in order to reduce human exposure to it. The clinoptilolite zeolite obtained from the Semnan area was characterized by X-ray diffraction pattern, FTIR spectroscopy and scanning electron microscopy (SEM). The central composite design (CCD) defin...
متن کاملA new Method for the Removal of Ammonium from Drinking Water Using Hybrid Method of Modified Zeolites / Catalytic Ozonation
Introduction: Ammonia in form of ammonium ions is toxic and could decrease the dissolved oxygen in water and endanger the aquatic life. The aim of this study is the removal of ammonium using oxidation and adsorption by catalytic ozonation and clinoptilolite zeolite, respectively. Methods: The research method is Experimental. First, optimal pH of ammonium adsorption on carbon catalyst (5 g/L), ...
متن کاملElimination of Copper (II) Ions from Aqueous Solution by the using of gamma alumina nanoparticles
heavy metals, as gamma alumina nanoparticles pollutants, in water resources. Therefore, the purpose of this paper was to evaluate the removal of copper (II) ions from aqueous solutions using gamma alumina nanoparticles as a adsorbent. Batch adsorption studies carried out to study various parameters included contact time, initial concentration of copper (II) ions, pH, and gamma alumina nanoparti...
متن کامل